Which command will create a static route on R2 in order to reach PC B?

The correct syntax is:
router(config)# ip route destination-network destination-mask {next-hop-ip-address | exit-interface}
If the local exit interface instead of the next-hop IP address is used then the route will be displayed as a directly connected route instead of a static route in the routing table. Because the network to be reached is 172.16.2.0 and the next-hop IP address is 172.16.3.1, the command is R2(config)# ip route 172.16.2.0 255.255.255.0 172.16.3.1